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Periodic trends & bondingAttractions between molecules

The idea

Attractions between molecules

Intermolecular forces act between molecules. Dispersion arises from fluctuating charge; hydrogen bonding is a stronger specific attraction in suitable molecules.
Why?

All atoms and molecules can develop temporary uneven electron distributions. Polarizability can make dispersion substantial. Hydrogen bonding requires H bonded to N, O or F interacting with an available ; boiling separates molecules rather than breaking all covalent bonds.

More detail

The model has a domain of validity. Explain its assumptions before using it in a changed context, then compare your prediction with evidence.

  • Intermolecular forces act between molecules. Dispersion arises from fluctuating charge; hydrogen bonding is a stronger specific attraction in suitable molecules.
  • Do not call every bond containing hydrogen a hydrogen bond. Dispersion is not always negligible.